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DR ANTHONY MELVIN CRASTO, WORLDDRUGTRACKER

A call to (green) arms: a rallying cry for green chemistry and engineering for CO2 capture, utilisation and storage

 green chemistry  Comments Off on A call to (green) arms: a rallying cry for green chemistry and engineering for CO2 capture, utilisation and storage
Sep 172018
 

Graphical abstract: A call to (green) arms: a rallying cry for green chemistry and engineering for CO2 capture, utilisation and storage

A call to (green) arms: a rallying cry for green chemistry and engineering for CO2 capture, utilisation and storage

 Author affiliations

Abstract

Chemists, engineers, scientists, lend us your ears… Carbon capture, utilisation, and storage (CCUS) is among the largest challenges on the horizon and we need your help. In this perspective, we focus on identifying the critical research needs to make CCUS a reality, with an emphasis on how the principles of green chemistry (GC) and green engineering can be used to help address this challenge. We identify areas where GC principles can readily improve the energy or atom efficiency of processes or reduce the environmental impact. Conversely, we also identify dilemmas where the research needs may be at odds with GC principles, and present potential paths forward to minimise the environmental impacts of chemicals and processes needed for CCUS. We also walk a different path from conventional perspectives in that we postulate and introduce potential innovative research directions and concepts (some not yet experimentally validated) in order to foster innovation, or at least stoke conversation and question why certain approaches have not yet been attempted. With elements of historical context, technological innovation, critical thinking, and some humour, we issue a call to arms and hope you may join us in this fight.

http://pubs.rsc.org/en/Content/ArticleLanding/2018/GC/C8GC01962B?utm_source=feedburner&utm_medium=feed&utm_campaign=Feed%3A+rss%2FGC+%28RSC+-+Green+Chem.+latest+articles%29#!divAbstract

STR1

Julien Leclaire

David Heldebrant

David Heldebrant

Pacific Northwest National Laboratory
PO Box 999
Richland, WA 99352

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Carboxylative cyclization of substituted propenyl ketones using CO2: transition-metal-free synthesis of [small alpha]-pyrones

 SYNTHESIS  Comments Off on Carboxylative cyclization of substituted propenyl ketones using CO2: transition-metal-free synthesis of [small alpha]-pyrones
Jul 292016
 

 

Carboxylative cyclization of substituted propenyl ketones using CO2: transition-metal-free synthesis of [small alpha]-pyrones

Green Chem., 2016, 18,4181-4184

DOI: 10.1039/C6GC01346E, Communication
Wen-Zhen Zhang, Ming-Wang Yang, Xiao-Bing Lu
Carboxylative cyclization of substituted 1-propenyl ketones via [gamma]-carboxylation using CO2 provides an efficient, straightforward, and transition-metal-free access to [small alpha]-pyrone compounds.

Carboxylative cyclization of substituted propenyl ketones using CO2: transition-metal-free synthesis of α-pyrones

*Corresponding authors
aState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, P. R. China
E-mail: zhangwz@dlut.edu.cn
Green Chem., 2016,18, 4181-4184

DOI: 10.1039/C6GC01346E

Carbon dioxide is a green carboxylative reagent due to its non-toxic and renewable properties. Described herein is a carboxylative cyclization of substituted 1-propenyl ketones via γ-carboxylation using CO2, which provides an efficient, transition-metal-free and straightforward access to important α-pyrone compounds from easily available substrates and CO2.
STR1
STR1
STR1

////////////Carboxylative cyclization, substituted propenyl ketones, CO2,  transition-metal-free synthesis,  [small alpha]-pyrones

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