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A green route for methanol carbonylation

spectroscopy, SYNTHESIS

Oct 092017

A green route for methanol carbonylation

Catal. Sci. Technol., 2017, Advance Article
DOI: 10.1039/C7CY01621B, Paper

Youming Ni, Lei Shi, Hongchao Liu, Wenna Zhang, Yong Liu, Wenliang Zhu, Zhongmin Liu
Halide-free and noble metal-free pyridine-modified H-mordenites exhibit high stability and selectivity in methanol carbonylation to acetic acid.

http://pubs.rsc.org/en/Content/ArticleLanding/2017/CY/C7CY01621B?utm_source=feedburner&utm_medium=feed&utm_campaign=Feed%3A+rss%2Fcy+%28RSC+-+Catalysis+Science+%26+Technology+latest+articles%29#!divAbstract

A green route for methanol carbonylation

Youming Ni,^a^b Lei Shi,^a^b Hongchao Liu,^a^b Wenna Zhang,^a^b^c Yong Liu,^a^b Wenliang Zhu*^a^b and Zhongmin Liu*^a^b

Author affiliations

*Corresponding authors

^aNational Engineering Laboratory for Methanol to Olefins, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China
E-mail: wlzhu@dicp.ac.cn, liuzm@dicp.ac.cn

^bDalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, PR China

^cUniversity of Chinese Academy of Sciences, Beijing 100049, PR China

Abstract

Acetic acid is one of the most important bulk commodity chemicals and is currently manufactured by methanol carbonylation reactions with rhodium or iridium organometallic complexes and halide-containing promoters named Monsanto or BP Cativa™ homogeneous processes, respectively. Developing a halide-free catalyst and a heterogeneous process for methanol carbonylation is of great importance and has recently attracted extensive research attention. Here, we report a green route for direct synthesis of acetic acid via vapor-phase carbonylation of methanol with a stable, selective, halide-free, and noble metal-free catalyst based on pyridine-modified H-mordenite zeolite. Methanol conversion and acetic acid selectivity can reach up to 100% and 95%, respectively. Only little deactivation is observed during the 145 hour reaction.

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