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Tout sur les médicaments הכל על תרופות كل شيئ عن الأدوية Все о наркотиках 关于药品的一切 డ్రగ్స్ గురించి అన్ని 마약에 관한 모든 것 Όλα για τα Ναρκωτικά Complete Tracking of Drugs Across the World by Dr Anthony Melvin Crasto, Worldpeacepeaker, worlddrugtracker, PH.D (ICT), MUMBAI, INDIA, Worlddrugtracker, Helping millions, 9 million hits on google on all websites, 2.5 lakh connections on all networks, “ALL FOR DRUGS” CATERS TO EDUCATION GLOBALLY, No commercial exploits are done or advertisements added by me. This is a compilation for educational purposes only. P.S. : The views expressed are my personal and in no-way suggest the views of the professional body or the company that I represent

trans-Cinnamamide , (2E)-3-Phenyl-2-propenamide

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Jun 272015

trans-Cinnamamide/(2E)-3-Phenyl-2-propenamide

Name	trans-Cinnamamide
Synonyms	(2E)-3-Phenyl-2-propenamide
Name in Chemical Abstracts	2-Propenamide, 3-phenyl-, (2E)-
CAS No	22031-64-7
EINECS No
Molecular formula	C₉H₉NO
Molecular mass	147.18
SMILES code	NC(=O)/C=C/c1ccccc1

1H NMR

¹H-NMR: trans-Cinnamamide
250 MHz, DMSO-d₆
delta [ppm]	mult.	atoms	assignment
6.61	d (J_AB= 15.9)	1 H	C=CH-CO (2-H)
7.13	broad s	1 H	NH
7.2-7.6	m	7 H	CH (arom.) + NH + -CH=C (3-H)
7.42	d (J_AB= 15.9)	1 H	-CH=C (3-H)
6.53	d	1 H	C=CH-CO (2-H, cinnamic acid)
7.82	d	1 H	-CH=C (3-H, cinnamic acid)
2.5	s		DMSO
3.33	s		O-CH₃ (tBu-OMe)
1.19	s		C-CH₃ (tBu-OMe)

¹³C-NMR

13C NMR

¹³C-NMR: trans-Cinnamamide
250 MHz, DMSO-d₆
delta [ppm]	assignment
122.31	C2 (=CH-)
127.52	CH arom.
128.90	CH arom.
129.42	C4 (arom.)
134.86	C quart. arom.
139.16	C3 (-CH=C)
166.68	C1 (-C(=O)NH₂)
38.5-40.5	DMSO-d₆

IR

IR: trans-Cinnamamide
[KBr, T%, cm^-1]
[cm^-1]	assignment
3375, 3175	N-H valence
3084	aliph. C-H valence, =C-H
1665	C=O valence, carboxamide
1610	alkene C=C valence
1580, 1495	arom. C=C valence

Chromatogram

crude product chromatogram

HPLC: crude product
column	Phenomenex Luna C18; particle diameter 3 µm, L= 150 mm, ID= 4.6 mm
column temperature	25 °C
injection	5 µL
mobile phase	5% MeCN / H2O (0.0059% CF3COOH), gradient to 95% MeCN / H2O (40 min), 10 min isocratic
flow	1.0 mL/min
detector (UV 220 nm)	percent concentration calculated from relative peak area

pure product chromatogram

HPLC: pure product
column	Phenomenex Luna C18, particle diameter 3 µm, Länge 150 mm, Innendurchmesser 4.6 mm
column temperature	25 °C
injection	5 µL
mobile phase	5% MeCN/H2O (0.0059% CF3COOH), gradient to 95% MeCN/H2O (40 min), 10 min isocratic
flow	1.0 mL/min
detector (UV 220 nm)	percent concentration calculated from relative peak area



Name	trans-Cinnamamide
Synonyms	(2E)-3-Phenyl-2-propenamide
Name in Chemical Abstracts	2-Propenamide, 3-phenyl-, (2E)-
CAS No	22031-64-7
EINECS No
Molecular formula	C₉H₉NO
Molecular mass	147.18
SMILES code	NC(=O)/C=C/c1ccccc1

NH₃

IR

IR: trans-Cinnamamide
[KBr, T%, cm^-1]
[cm^-1]	assignment
3375, 3175	N-H valence
3084	aliph. C-H valence, =C-H
1665	C=O valence, carboxamide
1610	alkene C=C valence
1580, 1495	arom. C=C valence

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Denpasar, bali, indonesia

Denpasar – Wikipedia, the free encyclopedia

https://en.wikipedia.org/wiki/Denpasar

Denpasar (Indonesian: Kota Denpasar, Indonesian pronunciation: [dənˈpasar]) is the capital and the most populous city of the Indonesian province of Bali.

‎Etymology – ‎History – ‎Geography – ‎Demography

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Jagatnatha Temple Denpasar | Bali Places to Visit

www.balisurfadvisor.com

Denpasar market, Denpasar is the capital of Bali Province. The main street of Denpasar is Gajah Mada street where is the main shopping center, .

A very giant Ogoh-ogoh at a cross junction in Denpasar

A view from the Kumbasari Market

PT (PERSERO) ANGKASA PURA I CABANG BANDARA NGURAH RAIGEDUNG WISTI SABHA LANTAI 3 BANDARA NGURAH RAIDENPASAR, BALI 80362

Bali Airport (Ngurah Rai) Denpasar – Indonesia

Bali Ngurah Rai International Airport, also known as Denpasar International Airport, is located in southern Bali, 13 km south of Denpasar. It is Indonesia’s third-busiest international airport.

Bajak Laut Nasi Tempong & Seafood, Renon, Bali

Sporting the growth of Denpasar residents’ likes for Nasi Tempong, Bajak Laut Nasi Tempong & Seafood sets on a different kind of path by combining Nasi Tempong with the other well-known Bali’s best: Seafood.

Sets in the cozy neighborhood of Renon, Denpasar, Bajak Laut is the newest addition of restaurant openings in this area. From the down-to-earth food courts selling Ayam Goreng, Chinese food and Sup Kepala Ikan, to the more luxurious XO Suki & Cuisine, Ayucious, or the more established Bendega, Ikan Bakar Cianjur, and Hanamasa, Bajak Laut further marks Renon as a leading Denpasar’s culinary destination.

Though opened really close to the market leader Nasi Tempong Indra, that with its aggressive market expansion in 2012 opens two new branches around Renon area alone, Bajak Laut however has what Indra has not: various choices of seafood comprising of fishes, shellfish, crabs, and shrimps. Therefore market wise, Bajak Laut is aiming at a slightly different crowds: those who loves the spicy Nasi Tempong, and those who loves Seafood; especially those too tired to go through all the traffic madness at Simpang Siur to reach Jimbaran.

(Or believes it’s too touristy.)

As the champion of this premise, Bajak Laut offers “Kepiting Asap ala Bajak Laut”, which are crabs cooked in sweet and savory rubs, then grilled inside banana leaf wraps to enhance its aroma. The result is a treat not only delicious to the taste but also to the sight.

Ingredients used for the rub is dominated with daun salam, or Indonesian bay leaves. For those familiar with gepuk; fried beef first marinated in spices and brown sugar, Kepiting Asap ala Bajak Laut has an almost identical seasoning.

One portion of Kepiting Asap ala Bajak Laut consisting of two crabs weighing total of 5 ons (500 grams). At 120K they’re good for two, while the 7 ons one costs 150K. For the 5 ons portion, the crab size is a bit small, hence eating them requires quite an effort.

Nasi Tempong is a good example how a food originated from outside Bali could becomes a local hit. Originated from Banyuwangi, Nasi Tempong managed to get quite followers due to its main character of super spicy sambal. Nasi Tempong usually served as a package consisting of white rice, steamed vegetables, tahu, tempe, anemic salted fish, and super spicy sambal, and a main dish of either fried chicken, or other kind of proteins.

While I’m not a die-hard spicy food fans, I found their Nasi Tempong quite palatable, especially since the stewed vegetables plus sambal that’s the core of every Nasi Tempong dish, is like a staple food in Western Java where I grew up.

Service is polite and attentive, though we found it’s a bit hard to get attention from the waiters, except from the one stand by the front door. Beside of the seafood, the Nasi Tempong variations are sold around 12K to 45K,

Starting December 2013 but don’t know for how long, Bajak Laut Nasi Tempong & Seafood offers a special discount for their set menu, at 150K for 4 people, and 250K for 6 people.

One annoying condition that we have to face as well, that even though the premise is fully airconed, people are allowed to smoke! And here in Denpasar, Bali, sadly it’s the common case with many eating premises, and Bajak Laut is no exception. Therefore while their crab is quite delicious, until Bajak Laut separates its smoking and non-smoking section it poses health hazard to your youngsters. (byms)

Bajak Laut Nasi Tempong & Seafood
Jl. Cok Agung Tresna No.23, Renon, Denpasar, Bali
(0361) 7984007

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11-Chloro-1-undecene

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Jun 272015

11-Chloro-1-undecene



Name	11-Chloro-1-undecene
Synonyms
Name in Chemical Abstracts	1-Undecene, 11-chloro-
CAS No	872-17-3
EINECS No
Molecular formula	C₁₁H₂₁Cl
Molecular mass	188.74
SMILES code	ClCCCCCCCCCC=C

SOCl₂

¹H-NMR

1H NMR

¹H-NMR: crude product
300 MHz, CDCl₃
delta [ppm]	mult.	atoms	assignment
1.1-1.5	m	12 H	CH₂
1.75	tt	2 H	2-H
2.02	dt	2 H	9-H
3.51	t	2 H	1-H
4.95	2xdd	2 H	11-H
5.80	m	1 H	10-H

1H NMR

¹H-NMR: 11-Chloro-1-undecene
300 MHz, CDCl₃
delta [ppm]	mult.	atoms	assignment
1.1-1.5	m	12 H	CH₂
1.75	tt	2 H	2-H
2.02	dt	2 H	9-H
3.51	t	2 H	1-H
4.95	2xdd	2 H	11-H
5.80	m	1 H	10-H

¹³C-NMR

13C NMR

¹³C-NMR: crude product
75.5 MHz, CDCl₃
delta [ppm]	assignment
32.7	C2
33.9	C9
45.0	C1
114.1	C11
139.1	C10
76.5-77.5	CDCl₃

13C NMR

¹³C-NMR: 11-Chloro-1-undecene
75.5 MHz, CDCl₃
delta [ppm]	assignment
32.7	C2
33.9	C9
45.0	C1
114.1	C11
139.1	C10
76.5-77.5	CDCl₃

IR

IR: 11-Chloro-1-undecene
[Film, T%, cm^-1]
[cm^-1]	assignment
3077	aliph. C-H valence, H₂C=C
2927, 2855	aliph. C-H valence
993, 910	deform. C-H, H₂C=C
723	C-Cl valence

Operating scheme

Chromatogram

crude product chromatogram

GC: crude product
column	DB-WAX, L=30 m, d=0.33 mm, film=0.25 µm
inlet	on column injection, 0.2 µL
carrier gas	H2, 40 cm/s
oven	90°C (5 min), 10°C/min –> 240°C (30 min)
detector	FID, 270°C
integration	percent concentration calculated from relative peak area

pure product chromatogram

GC: pure product
column	DB-WAX, L=30 m, d=0.33 mm, film=0.25 µm
inlet	on column injection, 0.2 µL
carrier gas	H2, 40 cm/s
oven	90°C (5 min), 10°C/min –> 240°C (30 min)
detector	FID, 270°C
integration	percent concentration calculated from relative peak area

8 must-see places in Southeast Asia for great views: bucket list 2015

Southeast Asia is more than food and culture; here are 8 eye-candy places with magnificent views for a highly memorable trip!

Not just a melting pot of cultures, religions, history and food, Southeast Asia offers many picturesque spots that your eyes will thank you for. Whether it’s enjoying a sunset from a mountain top or just taking in the bucolic sights of Mother Nature’s hand-sculpted terrains, you’ll attest that these 8 suggestions offer some pretty unique charms that take your breath away.

1. Inle Lake, Myanmar

Myanmar has become a hotspot for the intrepid traveller and opens up plenty of opportunities to lap up many of its natural scenic wonders. If you’re heading there, a must-see place is Inle Lake renowned for its vast body of water where one can spot fishing communities and homes built on stilts.

Not only is the lake famous for its photogenic quality, you can hire guides to visit fish farms and shop at handicraft stores. Inle Lake’s picturesque charm comes from watching leg-rowing fisherman haul their catch during sunset. Find cheap flights to the capital Naypyidaw and best time to travel there is between November and February.

Be mesmerised by the scenic Inle Lake in Myanmar

2. Tiger’s Nest Monastery, Bhutan

Perched some 3,000 metres above sea level and build in 1692, Bhutan’s Taktsang monastery, or more popularly known as Tiger’s Nest, is a must-see when you come to this nation steeped in Buddhist history. Getting there is not for the faint-hearted as one has to traipse through a hilly, rocky and undulating path to reach the peak.

Do hire guides to reach the apex successfully, and you’ll be rewarded by 360-views of sylvan mountain tops. Spring time from March to May is the best time to visit Bhutan and Drukair Royal Airlines of Bhutan flies theredirect.

Take in the lofty, airy views of Tiger’s Nest in Bhutan

3. Mount Kinabalu, Sabah, Malaysia

Recognised as one of the tallest peaks in Southeast Asia, Mount Kinabalu is a trekker’s dream come true. Getting to the summit takes about two days to accomplish. There is a 4-km climb to Laban Rata lodge where you can rest and replenish on sustenance. The next day is a 2-km climb to Low’s Peak.

The trek may be arduous but with lush rainforest terrain, there’s always something new at every corner to keep you distracted. About a kilometer away from the peak, the terrain changes to rock, stone and pebbles complemented by vegetation normally found in cooler climes. To catch the sunrise on the second day, it’s advisable to depart at 2am but remember to bring extra clothing as the mercury will drop to 2 degrees Celsius.

The scenic misty peaks of Mt. Kinabalu also offer spots for picturesque photos

4. Palawan Island, Luzon, Philippines

Recently coined by Huffington Post as “The Most Beautiful Island In the World” while Conde Nast Traveler’sReader Choice Awards named it “The Top Island in the World”, Palawan island is quite the magnificent sight. With its beautiful azure waters infused with emerald hues, it’s also hard to refute such claims.

Dotting the waters are jungled-filled islands, each with a distinctive hill rising above the ocean. Just by half-hour domestic flight from Manila airport, once you soar above Palawan’s oceanic landscape, you’ll feel like you’ve reached Shangri-la. Whether it’s island-hopping or sea kayaking, fun-filled times are never in short supply.

The beaches of Palawan have powdery white sand!

5. Penang National Park, Malaysia

Penang is truly a foodie paradise but many people are flocking there for other reasons, one being its attractive natural environment. Located just west of mainland Malaysia, a flight from Singapore is slightly over an hour.

With plenty of diverse lifestyle choices and entertainment options, Penang also has its idyllic charms. Aside from its UNESCO-designated George Town, the Penang National Park located on the North-Western side of the island rewards one with rich rainforests, a diverse ecosystem and some 1,381 hectares of wetlands to indulge trekking fanatics and eco-photographers.

6. Tanah Lot Temple, Bali, Indonesia

Bali is never in short supply of mysticism and wonder. A two-hour flight out of Singapore is all it takes to enjoy a short vacation. And of course, visiting its picturesque sea temple on the west coast of Bali, Tanah Lot, promises many Kodak moments. A simple traipse during low-tide rewards a sight to behold too – a Hindu shrine ensconced among lush trees perched on a rock is postcard-worthy from any angle. Framed by crashing waves, Tanah Lot Temple brims with a dab of fable and mysticism that makes it a must-see when visiting Bali!

Tanah Lot in Bali offers scenic views of splendid structures amidst crashing waves

7. Angkor Wat, Siem Reap, Cambodia

Angkor Wat became even more famous, thanks to the Tomb Raider movie starring Angelina Jolie. Founded in the 12th Century, it is also the 7th Wonder of the World. This Khmer temple’s architecture will seize the gaze of any first-time visitor. At the centre of this city, within a moat, is a towering stupa that provides sylvan views of its 3.6km, vine-covered outer wall. Just 5.5km north of Siem Reap, the Angkor Archaeological Park is a must-see for travellers with a penchant for history and artefacts.

Angkor Wat’s lush views are both captivating and mysterious

8. Halong Bay, Hanoi, Vietnam

Halong Bay, which means “Bay of Descending Dragons”, is a unique karst topography carved out by Mother Nature. The UNESCO World Heritage site offers views of vertical formations which are rich in dense vegetation. A boat cruise meandering through any of the 1,969 islets is both tranquil and insightful. Avoid the monsoons from June to September and from January to March, but visit the high seasons to enjoy sunny skies that won’t put a damper on your exploration plans of the natural outlying islets. After a three-hour fight to Hanoi from Singapore, take a five-hour road trip via mini bus to the port; it costs around USD 6 (SGD 7.50) and can be arranged upon arrival.